Mechanical and Thermal Properties of Lead Borate Glasses Containing CaO and NaF

Kh S. Shaaban; Y. B. Saddeek; M. A. Sayed; I. S. Yahia

doi:10.1007/s12633-017-9709-8

Mechanical and Thermal Properties of Lead Borate Glasses Containing CaO and NaF

Kh S. Shaaban
, Y. B. Saddeek
, M. A. Sayed
, I. S. Yahia

Al-Azhar University
King Khalid University
Ain Shams University

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

Glasses with the chemical composition 39PbO - 1NaF - (60-x){0.667B₂O_3-0.333Na₂O } – x CaO (x = 0, 5, 10, 15, 20, and 25 mol %), were prepared by the usual melt quenching technique, and analyzed by using X-ray diffraction, density, differential thermal analysis (DTA), optical properties and mechanical properties. The structural variations due to the increase of the [BO₄] at the expense of [BO₃] structural units increase the ultrasonic velocity and the elastic moduli along with an increase of the density. The Makishima–Mackenzie model was applied successfully on the prepared glasses. The elastic moduli according to this model increase, which was due to the increase of CaO content. The increase of the glass transition temperature (T_g) according to DTA confirmed this behavior.

Original language	English
Pages (from-to)	1973-1978
Number of pages	6
Journal	Silicon
Volume	10
Issue number	5
DOIs	https://doi.org/10.1007/s12633-017-9709-8
State	Published - 1 Sep 2018
Externally published	Yes

Keywords

DTA
Elastic moduli
Lead borate glasses

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10.1007/s12633-017-9709-8

Cite this

@article{b16a207084cb4540877edb12357d6e95,

title = "Mechanical and Thermal Properties of Lead Borate Glasses Containing CaO and NaF",

abstract = "Glasses with the chemical composition 39PbO - 1NaF - (60-x)\{0.667B2O3-0.333Na2O \} {\textendash} x CaO (x = 0, 5, 10, 15, 20, and 25 mol \%), were prepared by the usual melt quenching technique, and analyzed by using X-ray diffraction, density, differential thermal analysis (DTA), optical properties and mechanical properties. The structural variations due to the increase of the [BO4] at the expense of [BO3] structural units increase the ultrasonic velocity and the elastic moduli along with an increase of the density. The Makishima{\textendash}Mackenzie model was applied successfully on the prepared glasses. The elastic moduli according to this model increase, which was due to the increase of CaO content. The increase of the glass transition temperature (Tg) according to DTA confirmed this behavior.",

keywords = "DTA, Elastic moduli, Lead borate glasses",

author = "Shaaban, \{Kh S.\} and Saddeek, \{Y. B.\} and Sayed, \{M. A.\} and Yahia, \{I. S.\}",

note = "Publisher Copyright: {\textcopyright} 2017, Springer Science+Business Media B.V., part of Springer Nature.",

year = "2018",

month = sep,

day = "1",

doi = "10.1007/s12633-017-9709-8",

language = "English",

volume = "10",

pages = "1973--1978",

journal = "Silicon",

issn = "1876-990X",

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number = "5",

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TY - JOUR

T1 - Mechanical and Thermal Properties of Lead Borate Glasses Containing CaO and NaF

AU - Shaaban, Kh S.

AU - Saddeek, Y. B.

AU - Sayed, M. A.

AU - Yahia, I. S.

PY - 2018/9/1

Y1 - 2018/9/1

N2 - Glasses with the chemical composition 39PbO - 1NaF - (60-x){0.667B2O3-0.333Na2O } – x CaO (x = 0, 5, 10, 15, 20, and 25 mol %), were prepared by the usual melt quenching technique, and analyzed by using X-ray diffraction, density, differential thermal analysis (DTA), optical properties and mechanical properties. The structural variations due to the increase of the [BO4] at the expense of [BO3] structural units increase the ultrasonic velocity and the elastic moduli along with an increase of the density. The Makishima–Mackenzie model was applied successfully on the prepared glasses. The elastic moduli according to this model increase, which was due to the increase of CaO content. The increase of the glass transition temperature (Tg) according to DTA confirmed this behavior.

AB - Glasses with the chemical composition 39PbO - 1NaF - (60-x){0.667B2O3-0.333Na2O } – x CaO (x = 0, 5, 10, 15, 20, and 25 mol %), were prepared by the usual melt quenching technique, and analyzed by using X-ray diffraction, density, differential thermal analysis (DTA), optical properties and mechanical properties. The structural variations due to the increase of the [BO4] at the expense of [BO3] structural units increase the ultrasonic velocity and the elastic moduli along with an increase of the density. The Makishima–Mackenzie model was applied successfully on the prepared glasses. The elastic moduli according to this model increase, which was due to the increase of CaO content. The increase of the glass transition temperature (Tg) according to DTA confirmed this behavior.

KW - DTA

KW - Elastic moduli

KW - Lead borate glasses

UR - https://www.scopus.com/pages/publications/85037984175

U2 - 10.1007/s12633-017-9709-8

DO - 10.1007/s12633-017-9709-8

M3 - Article

AN - SCOPUS:85037984175

SN - 1876-990X

VL - 10

SP - 1973

EP - 1978

JO - Silicon

JF - Silicon

IS - 5

ER -

Mechanical and Thermal Properties of Lead Borate Glasses Containing CaO and NaF

Abstract

Keywords

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