Impact of gamma irradiation on optical and nonlinear properties of Indium chloride phthalocyanine thin films

This study investigates the impact of gamma radiation on indium chloride phthalocyanine (lnPcCl) thin films, which were prepared via vacuum thermal evaporation. x-ray diffraction revealed the amorphous structure of the films, with increasing gamma doses causing more noticeable structural disorders. Optical analysis showed a slight decrease in the optical band gap energy and a significant reduction in the fundamental band gap energy. Additionally, higher gamma doses led to decreased transmittance and increased reflectance. The study also observed substantial enhancements in nonlinear optical parameters, such as third-order nonlinear susceptibility (χ⁽³⁾) and nonlinear refractive index (n ₂). These findings suggest the potential of gamma-irradiated lnPcCl films for advanced optoelectronic and nonlinear optical applications.