Comparative analysis of delamination resistance in CFRP laminates interleaved by thermoplastic nanoparticle: Evaluating toughening mechanisms in modes I and II

The study considers the delamination resistance of carbon/epoxy laminates modified with Thermoplastic Nanoparticles of Polysulfone (TNPs). A new electrospinning nanofiber technique was utilized to convert polysulfone polymer into nanoparticles and uniformly disperse them within the resin. Fracture toughness was evaluated under loading modes I and II. In mode I, the toughness (G_IC) increased significantly from 170 to 328 J/m² with TNPs incorporation. However, mode II showed minimal change, with G_IIC values of 955 J/m² for virgin and 950 J/m² for TNPs-modified specimens. Scanning Electron Microscopy (SEM) was employed to depict the influence of TNPs on damage characteristics and crack propagation patterns. In mode I, crack deviation enhanced toughness as TNPs bypassed the PSU, while in mode II, cracks propagated through TNPs, resulting in particle smearing on the epoxy surface. This highlights TNPs' potential to modify the fracture toughness in mode I loading, but their effect is constrained in mode II loading scenarios.